1.
Chem Commun (Camb)
; 60(8): 1043-1046, 2024 Jan 23.
Artigo
em Inglês
| MEDLINE
| ID: mdl-38174921
RESUMO
We describe the synthesis and characterisation of four organic Lewis acids based on fluorophosphoniums, with tetracarbonyl cobaltate as the counter-anion: [R3PF]+[Co(CO)4]- (with R = o-Tol, Cy, iPr, and tBu). Their catalytic activity was investigated for the carbonylation of ß-lactones to succinic anhydrides. In the presence of [tBu3PF]+[Co(CO)4]- IV (3 mol%), 90% of succinic anhydride was afforded from ß-propiolactone after 16 h at 80 °C, at a very mild pressure of 2 bar of carbon monoxide. Our study sets the first example of the use of a main-group cation as a Lewis acidic partner in the cobalt-catalyzed carbonylation of ß-lactones.